Molecular rivets keep porous COFs from collapsing in humid air, benefiting water harvesting, dehumidification, heat pumps
https://phys.org/news/2025-09-molecular-rivets-porous-materials-collapsing.html "mesoporous keto-enamine-linked COFs show enhanced framework physical stability due to intralayer hydrogen bonds... COFs adsorb/ release water vapor, capillary forces exerted within shift layers, collapse channels, transform frameworks into amorphous polymers...trade-off: smaller pores more stable, hold less water/ larger pores stored more water, collapse under capillary forces... overcome using keto-enamine linkages creating intralayer hydrogen bonds holding layers rigidly together, preventing interlayer slipping" Related: How atmospheric water harvesting can be scaled https://techxplore.com/news/2025-09-atmospheric-harvesting-scaled.html Uncovering diverse water adsorption characteristics in metal–organic frameworks https://phys.org/news/2025-10-uncovering-diverse-adsorption-characteristics-metalorganic.html Cooling paint harvests water from thin air https://www.eurekalert.org/news-releases/1104...